Are you using Scheme or Common Lisp? For MIT Scheme or similar, you might want to take the Emacs tutorial in Edwin instead (start MIT Scheme with the "-edit" flag) since it contains Scheme-specific commands. Also check out http://www.gnu.org/software/mit-scheme/ and follow the directions to install xscheme.elc - it gives you a Scheme-mode optimized for MIT Scheme. This doesn't compare to SLIME mode for Common Lisp, but I don't know of a good substitute.
That said, there are QUITE a lot of Emacs and Scheme-mode commands, and the only way to learn them is through use. Once you're familiar with the basics (motions and evaluating), you might take a list of commands you want to master and put up two or three at a time, making a point of using them. Here's a very limited and basic set of Emacs/Scheme commands: http://github.com/bcdarwin/SICP/blob/master/emacs_bindings_s...
There is also customization via the .emacs file or Emacs Lisp programming; see the Emacs info documentation or the O'Reilly books on this.
Emacs also has a built-in repl, the Interactive ELisp Mode. Hit M-x (alt-x) and type ielm (your cursor will have jumped down to the minibuffer below the mode line) and hit enter. You'll find yourself in a buffer with an elisp prompt, where you can use tab completion and elisp's doc functions to do a lot of learning:
(documentation FOO)
(apropos STRING)
documentation finds the docstring attached to function FOO and apropos searches for functions whose names match STRING.Emacs is my primary programming environment but thus far DrScheme beats Emacs with it's visual debugger and stepper - it is perfect for learning.