I'm a little out of my depth, but is there a reason they don't use something like a sealed lead-acid marine battery, rather than a big pile of D-cells?
Modulo correct wiring, if you have a massive stack of D-cells and one dies, it's not a big deal. If your sole source of power dies, then you either have to send out a repair crew (expensive!) or have no data until the buoy is replaced on-schedule.