Facebook and Snapchat will begin to be perceived as a 'utility' (something that has already happened to Twitter), meaning, we as a society all expect these functions of social networking and messaging to be fulfilled by a provider, but the exact provider is no longer relevant. Pressures to maintain a positive balance sheet will lead to a proliferation of ads.
This will leave room for new upstarts to target a niche they can serve better than the incumbents, and lure engagement away. They will use VC money to fund their effort and offer ad-free, carefully-focused refuges away from the big networks. But the incumbents have so much money, they will all get bought out in the end. (Snapchat refused to be bought out by Facebook for $3,000,000,000, at a time when it was still known as a sexting app)
I see analogues to the churn of free image hosts -- new one starts up because all the old ones are full of ads; introduces ads a few years later because they can't pay the bills. The cycle continues.