An example of this would be the CSS Box Model, which had reference implementations in both IE and NN at the time the spec was written. The spec changed how width was calculated, leaving every existing browser incompatible, and leading to silly things like Netscape.com not rendering correctly in the first released version of Netscape 6.
Nowadays, it's a mystery why MS gets left out of the loop. The standards committees are still non-MS dominated, so conspiricy-theorists could conclude that there's still some collusion between the Mozilla & WebKit teams and the W3. Or it could simply be Microsoft not wanting to get burned yet again.
There's a reason why Twiddla is so fast on IE. It's because we intentionally leave the Doctype of the whiteboard, thus enabling IE to use its fast Quirksmode rendering engine. Testing showed that adding a Doctype didn't effect FF or Chrome performance at all, but simply slowed IE down to their level.