EDIT: For my part I've never worked for anyone asking for an opt-out, and I'd never sign an opt-out, and I would sue if I suspected an employer punished me for not signing an opt-out.
EDIT2: Here's the UK government advice on the opt-out [1]. Note: "Your employer can ask you to opt out, but you can’t be sacked or treated unfairly for refusing to do so. You can opt out for a certain period or indefinitely. It must be voluntary and in writing." Additionally there are exceptions for a very small set of types of workers [2].
[1] https://www.gov.uk/maximum-weekly-working-hours/weekly-maxim...
[2] https://www.gov.uk/maximum-weekly-working-hours/overview