Here two of the best voxel editors:
https://voxel.codeplex.com/ http://guillaumechereau.github.io/goxel/
https://voxel.codeplex.com/ http://guillaumechereau.github.io/goxel/
I'm the coder of Smith and Winston [http://www.indiedb.com/games/smith-winston] and we've found Qubicle to be the best by far.