The first claim seems to be incorrect at least based on simple googling to obtain the following link: https://www3.epa.gov/climatechange/ghgemissions/global.html
According to that link agriculture/land-use appears to have about 1/6 the impact of industrial processes/fossil fuel.
The second claim appears to be incorrect for "human produced" CO2 at least, using standard numbers. Perhaps there is another source?
https://en.wikipedia.org/wiki/List_of_countries_by_carbon_di...
Summing up the numbers there, I get the following results:
Annual CO2 Emissions:
(China): 10,540,000 kt
(USA + Canada + Mexico + Brazil + Argentina + Venezuala): 7,245,000 kt