I use Hangouts at work because it's easy to get it on the screens in our office. I don't use VoIP in my personal life much, and never on a computer, I'd rather use a phone (and therefore either a phone call, or Signal).
By it you mean Wire.com? interesting. Do you allow Wire.com access to your address book on your mobile device? See https://news.ycombinator.com/item?id=11288169