>the presence of mountain goats and bighorn sheep
Perhaps you should watch the second part, which is about domestication. He addresses this point in this part (you seem to have missed it) but explores it more in the second. Some animals are not domesticatable (e.g. zebras) despite seeming that they could be. It isn't like he came up with his list of potential targets of domestication off of the top of his head. There's a reason stuff like bears and deer aren't on it. And he only used bison as an example of something that would be profitable if it was domesticated, but it can't be by pre-modern societies.
1: "With dogs, herding sheep and cattle is easier. Now humans have a buddy to keep an eye on the clothing factory, and the milk and cheeseburger machine, and the plow-puller."