You do start to see some odd effects at those voltages though - I recall holding one of the output plates for ten minutes or so, without realising the supply was on. Didn't really think much of it, until I realised I could hold my hand over a piece of tin foil (roughly 1cmx1cm) and it would be attracted to my hand from 2-3cm away (that persisted for five minutes or so).
In practice pretty much everyone who designs safety critical systems where electrocution is a concern focuses on current because it's a much better way to model and analyze the system risks than voltage.
Stuff like radon or CO are way higher on that list, in my personal opinion. Hell, even people's general ignorance of their countries' political process and what their (elected or not) officials are doing is way more frightening to me than their ignorance about electricity.
Sorry to be so damn pedantic.
Including but not limited to: software, nuclear radiation, CO and chemistry in general, electricity, microbiology, politics in practice, macro-economics and banking, ... (it's a pretty long list)