I'm glad they are getting into this, competition is always good. With the pricing page giving a 404 I can only guess that it will cost more than Let's Encrypt, but if you haven't already rolled your own, it might be a nice option.
20 domains on an ELB for a year, $10.80 per domain (ignoring traffic). Or put 5x as many on and get SSL for $2.16 per domain per year (also ignoring traffic).
That said, I'm really happy to see AWS head this way. Even if someone uses them, in min mind Let's Encrypt did its job - drive the cost of SSL down to where everyone can have it.
With more than one web server you need to be able to server that file up on any instance that might get hit when the challenge request comes in.
For some, DNS might be an easier way to prove domain ownership, but we have clients who control their DNS. Doing it all on the web means it is 100% in our hands.