I find that most of my beginner friends tire quickly of the long, drawn-out, exaggerated drama and dramatic music of Italian operas (i.e. Tosca, La Bohème, etc.). Some comedy sprinkled in together with an interesting plot can keep newbies interested for much longer.
I would recommend starting with some of Mozart’s lightest and craftiest operas (e.g. Cosí Fan Tutte, The Marriage of Figaro, The Magic Flute). And of course, watch Amadeus first.