No, I don't think DJ Shadow can be automated, but live DJing is a music discovery channel for only a scant minority of fans. These fans are sometimes called "trainspotters."
Radio DJs, on the other hand, have any number of forces affecting their song choices (to the degree the role exists at all anymore), and all in all they're just as much a black box as an algorithm. Sure, we all had radio shows we liked for some time, but those DJs changed and we found something else (notwithstanding people who have been listening to "Renee and Crazy Pete in the morning" for 20 years).
Even with all of this, I suspect there's a discrete economic or mathematical reason that profit-oriented discovery engines regress to a mean and will always be trying to recommend the latest AdeleBieberNational. They may not, right away, but a few clicks deep in the sidebar and you find LL Cool J or Foo Fighters popping up.