There are also other characteristics that come into play. With digital sensors, you're capturing colors as seen by the color matrix on top of the sensor; Nikon, Canon, and Sony make these differently. With film, you're physically activating dye, and the dyes are also chosen uniquely for each film. So the colors can end up looking different, both because of process difference and intentional changes of the color. (Velvia 50 does not provide what one would call accurate color, but the inaccuracy is quite pleasing. The same goes for the Kodachrome/Ektachrome which were very popular in their times.)
On digital - when the pixel goes to 255 light intensity, it's just gone. There's no way to recover data that isn't there. The Magic Lantern firmware has the ability to scan out lines alternating between high and low ISOs to capture blown-out areas, but it's not perfect either.
"Modern" films tend to be very well-behaved with regards to these kind of characteristics, actually. Acros 100 has virtually no reciprocity failure - for exposures between 2 minutes and 10 minutes you need to add 1/2 stop of light. I've recovered pictures off negatives with virtually no visible exposure. The tonality is great and the grain is virtually invisible even with Rodinal. The new Portra 400 is also extremely forgiving - you can get something workable up to about ISO 1600 or 3200 with standard processing, and if you push process (develop longer) it's even better.
I have some Provia 100F which works to something like 160 seconds, I will try that in the future for long exposures.
I haven't tried the Portra films yet, as I mostly do landscapes, not portraits, and prefer Fuji's inaccurate colors for that application. (Ektar is a bit more muted color-wise, which yields a nice calming effect: https://goo.gl/photos/jMLY9UwS5Uwn2TQW7 )
One other thing: digital camera tend to get rated on shadow detail, not highlight detail, so their built-in light meters tend to "expose to the right", discarding highlights in favor of collecting more shadow detail. If you meter off an 18% grey card, a real light meter tends to give a shorter exposure than the camera's built-in meter, better preserving highlights. As someone who likes a well-defined sky, I'm betrayed by the camera manufacturers here. (But you'll of course notice it on the screen, and you can just turn the exposure compensation wheel to underexpose, and you're golden. It is not quite so easy with slide film, involving a lot of measurements and very careful spot metering. Therein lies the fun.)
I've messed with these a bit: https://www.google.com/nikcollection/
They're a step above your typical Instagram-type filters and you can tweak effect parameters and strength depending what you're going for. It can easily devolve into gimmickry and I'm sure a skilled photographer and editor can do more without presets/plugins but for the average or hobbyist photographer I've found them to be a good starting point.