It's also nice that I don't have to signup anywhere to use most IRC servers.
Don't get me wrong—Slack is the perfect tool for businesses, but not for much else.
I hate that argument. If decentralized was so great, then it'd be more popular, but it's not. More and more centralized stuff is exploding in popularity.
That is, the network can be decentralized but still administered by a single business entity, in which case you theoretically get a network more robust to outages, or the network can be composed of many separate entities, in which case you are theoretically protected from the bad behavior of any one administering entity, since there are many others (as in your example).
The other reason it may be harder to build a business atop a decentralized network is that the costs associated extra hardware, software, and locations and troubleshooting required to achieve the gains of a decentralized network may outweigh the gains achieved by doing so.
Decentralized systems, and peer-to-peer systems, and even centralized systems designed around computers designed to sit next to a wall outlet and draw power from a practically unlimited source are all being replaced by systems that are more centralized and better equipped to talk to mobile. AOL Instant Messenger is dying because it was built around an older paradigm and, at least last time I bothered to try it, is an incredible battery drain on Android devices. Newer messenger apps that are built mobile first or at least make mobile an equal partner to PCs are winning instead. And it's the same for group chat -- IRC is built for old-fashioned PCs, Slack is built with mobile in mind.
Such facilities are bolted onto IRC, but never truly integrate with it the way other solutions have offered.