Of the 6 founders of Excite, 5 were Stanford computer science graduates.
Jerry Yang and David Filo, founders of Yahoo, were electrical engineering graduates (thus very tech oriented).
Alta Vista was started by some electrical engineers and computer scientists from DEC.
Inktomi was started by Eric Brewer who was an electrical engineering and computer science professor.
I'm sure there are more.
EDIT:
As the NYT article noted, Google was swimming against the tide at the time. History has proved them right.
It should be mentioned that Sergey and Larry recruited Eric Schmidt as CEO in 2001. Eric is a hugely capable computer scientist, but he also had a proven record as CEO at Novell. In essence they brought in a 'business guy' who they trusted with the technical aspects of Google.