Properly theming (at least in 3.x) took a lot of effort. Just try to make a theme whereby at first glance, you can't tell that Bootstrap was used. It's not that it's not possible to do, it just took a lot of time and effort to nitpick over every detail.
In professional environments (ie: real flesh and blood companies), developers cannot say "we're using Bootstrap's default theme". The business has designers, the designers come up with a design, and unless the developer can customize Bootstrap to accommodate the requirements, in a reasonable amount of time to meet deadlines, Bootstrap is simply not an option outside of using the grid system.