On the flip side, if you're doing a security test like this, I've gotten mileage out of convincing apps to access local resources with things like 127.88.23.245, precisely because the developer blocked 127.0.0.1 specifically and thought they were done.
You should also usually block all internal and external IPs for your entire network, but especially in the cloud this can begin to get tricky. Still, you should.
And don't forget IPv6.